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Huang, el al., reported in early 2019 that the advancement and increasing interests in green energy production and environmental protection technologies have spurred the demand for rare-earth elements. On the other hand, the U.S. has to rely 100% on import of these materials as the industry was crashed because of the environmental issues associated with mining and processing, and more importantly by a lack in competitiveness.

As rare earth elements have many applications in defense and national security sectors, some of the elements were listed as strategic materials or critical materials because of the uncertainties in supply and prices. Therefore, it has become imperative in searching for alternative resources for supplying rare earth elements including unconventional resources.

With the strong incentive, coal fly ash is identified as one of the candidates among them. In this study, we present rare earth element data for the 42 ash samples (all derived from Powder River Basin coal) that we collected from seven states (UT, WY, IO, WI, ND, CO, and MI) representing 158 million tons of fly ash. The results indicate  scattered distributions of rare-earth elements with concentration ranging from 156 to 590 ppm although all the ash samples originated from the same coal basin (Powder River Basin). The rare earth element resource in these ashes is estimated between 74,000 to 106,000 tons.

The ash samples were also characterized by Elemental analysis, XRD, SEM-EDS, and BET surface area. The characterizations of the ashes were discussed as they might have  implications in the subsequent rare earth element extraction processes. In summary, fly ash may represent a potential resource for rare earth element production.

See Journal: https://www.sciencedirect.com/science/article/pii/S1002072119300274

 

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