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In this study, Day, et al., examined a coherent geochemical dataset for 24 shergottites and 16 nakhlites that highlights fundamental differences in their incompatible trace-element compositions. These trace-element differences can be explained by melting of metasomatized mantle sources, likely the martian lithosphere, for nakhlites and chassignites, and deep mantle plume sources for shergottites. Combined with Sr-Nd isotope variations and geophysical evidence for high effective elastic thickness of the martian lithosphere (≥150 km), these data are consistent with generation of shergottites from mantle plume partial melts and nakhlites and chassignites from lower degree partial melting of hydrated mantle during loading of the martian lithosphere. These modes of formation for martian meteorites are analogous to Hawaiian main shield and rejuvenated volcanism, respectively. Instead of loading of moving oceanic lithosphere above a stationary hotspot, however, Mars manifests dynamic support of thick lithosphere by static mantle plumes, and the generation of large volcanic loads and the largest volcanoes in the Solar System.

Direct analysis of the composition of Mars is possible through delivery of meteorites to Earth. Martian meteorites include ∼165 to 2400 Ma shergottites, originating from depleted to enriched mantle sources, and ∼1340 Ma nakhlites and chassignites, formed by low degree partial melting of a depleted mantle source. To date, no unified model has been proposed to explain the petrogenesis of these distinct rock types, despite their importance for understanding the formation and evolution of Mars. Here we report a coherent geochemical dataset for shergottites, nakhlites and chassignites revealing fundamental differences in sources. Shergottites have lower Nb/Y at a given Zr/Y than nakhlites or chassignites, a relationship nearly identical to terrestrial Hawaiian main shield and rejuvenated volcanism. Nakhlite and chassignite compositions are consistent with melting of hydrated and metasomatized depleted mantle lithosphere, whereas shergottite melts originate from deep mantle sources. Generation of martian magmas can be explained by temporally distinct melting episodes within and below dynamically supported and variably metasomatized lithosphere, by long-lived, static mantle plumes.

Comparative planetology relies on assumptions that physical processes occurring for Earth can be used to compare with processes acting on other planetary bodies. This logic has been applied to Mars, where the broadly basaltic surface composition has been considered analogous to volcanism in terrestrial hotspot locations, including Hawaii. Large volcanic edifices on Mars, including Olympus Mons, Alba Patera, Elysium, Arsia, Pavonis, and Ascraeus have been attributed to partial melting above mantle plumes. Mars does not appear to have had plate tectonics, implicating long-lived and static volcanism above mantle plumes, in contrast to age-progressive volcanism occurring in oceanic and continental settings on Earth. This difference, coupled with the distinct thickness and flexural rigidity of the elastic lithosphere on both planets, make assumptions of similar volcano-magmatic processes challenging. For example, observed pre-shield, shield, post-shield erosional, and rejuvenated stages of volcanism observed in Hawaii have not been recognized for Mars owing to the lack of plate motion.

Direct and precise geochemical observations for Mars are possible by analysis of meteorites recognized as having a martian heritage, from trapped Ar, Xe, and N2 signatures identical to the martian atmosphere, and by their distinct oxygen isotope compositions. These meteorites, which represent near-surface extrusive or hypabyssal intrusive rocks within the martian crust, including shergottites, nakhlites and chassignites, and ancient (4100–4400 Ma) crustal rocks (ALH 84001; NWA 7034/7533 and their pairs), are the ground truth for remote sensing. Shergottites are the most geochemically diverse group of martian meteorites. They span a range of compositions, with evidence for long-term incompatible trace-element-depleted and trace-element-enriched reservoirs in Mars that were formed as early as ~4504 Ma. Originally, the incompatible-element-depleted reservoir was considered to represent the mantle and, the incompatible-element-enriched reservoir, the crust15. This straightforward interpretation has been increasingly challenged by petrological, geochemical, and isotopic data, indicating the presence of both incompatible-element-depleted and incompatible-element-enriched martian mantle reservoirs.

The geochemical identity of shergottite source reservoirs is well expressed in 87Sr/86Sr–143Nd/144Nd space, where samples are corrected for ingrowth from 87Rb and 147Sm decay since crystallization. Shergottites define long-term Rb and Nd-depleted, intermediate, and -enriched groups and, collectively, span compositions a factor of four greater than found in terrestrial ocean island or mid-ocean ridge basalts. The 1270–1420 Ma (average of 1340 ± 40 Ma) nakhlites and chassignites are isotopically distinct from shergottites, with depleted Sr and Nd isotope compositions. Nakhlites (clinopyroxene-rich mafic rocks) and chassignites (dunites) are petrogenetically associated low-degree partial melts from the same depleted mantle source. The relationship of nakhlites and chassignites to shergottites is poorly understood. Both depleted shergottites and nakhlites have 142Nd enrichments consistent with early-formed Sm/Nd-enriched mantle sources, but 182W and 142Nd data for nakhlites indicate a more complex origin than for shergottites that cannot be explained by early silicate differentiation alone. Instead, late incompatible-element source enrichment must have occurred between major silicate differentiation at 4504 Ma and crystallization of the nakhlites at ~1340 Ma.

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