Singh and five co-authors reported in early 2014 that uraninite (UO2) is the most desirable end product of in situ bioreduction because of its low solubility under reducing conditions. For effective long-term immobilization of uranium (U), there should be no biotic or abiotic reoxidation of the insoluble biogenic U(IV). It is therefore critical to understand the long-term stability of U(IV) under oxic- and nutrient-limited conditions at U-contaminated subsurface sites.
The authors have established that following in situ bioremediation of U(VI) via nutrient addition in the subsurface, a range of physical, chemical, and biological factors control the rate and extent of long-term stability of U(IV). Some of these factors are tied to site specific conditions including existence of oxidants such as Fe(III)(hydr)oxides, Mn(IV) oxides, oxygen, and nitrate; the presence of organic carbon and the reduced forms of U (e.g., mononuclear U(IV) or nanometer-sized uraninite particles); and the carbonate concentration and pH of groundwater.
The authors analyzed the contribution of these factors in controlling U(IV)-reoxidation, and highlights the competition among U(IV) and other electron acceptors and possible mechanisms of reoxidation of various forms of U(IV).
Original working URL: https://www.tandfonline.com/doi/abs/10.1080/10643389.2012.728522
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